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王官武

王官武出生于1966 年,四川富顺人。中国科学技术大学化学系教授、博士生导师、中国科学院"百人计划"入选者、国家杰出青年科学基金获得者。

1983-1987,本科,兰州大学化学系

1987-1990,硕士,兰州大学化学系(导师:刘有成院士)

1990-1993,博士,兰州大学化学系 (导师:刘有成院士)

1993-1995,复旦大学化学系(吴世晖教授)

1995-1996,京都大学化学研究所(小松?一教授)

1996-1997,肯塔基大学化学系(Mark S. Meier教授)

1997-1998,芝加哥大学化学系(Philip E. Eaton教授)

1999-2000,耶鲁大学化学系(Martin Saunders院士)

2000- 中国科学技术大学化学系

2001.7-8, 京都大学化学研究所访问教授

富勒烯化学、绿色化学、计算化学、分子化学

1999年度中国科学院"引进海外杰出人才"计划("百人计划")入选者

2001年度国家杰出青年科学基金获得者

2001年度中国科学技术大学"张宗植青年教师奖"

2003年度国家自然科学基金委创新研究群体骨干成员

2004年入选国家七部委首批"新世纪百千万人才工程"

2007-2012

1. Wang, G.W.; Li, F. B., Transition Metal Salt-Mediated Radical Reactions of 60Fullerene. Current Organic Chemistry 2012, 16, (9), 1109-1127.

2. Wang, G.W.; Gao, J., Solvent-free bromination reactions with sodium bromide and oxonepromoted by mechanical milling. Green Chemistry 2012, 14, (4), 1125-1131.

3. Su, Y. T.;Wang, Y. L.; Wang, G. W., Palladium-catalysed heteroannulation of 60 fullerenewith N-benzyl sulfonamides and subsequent functionalisation. Chem Commun 2012,48, (65), 8132-8134.

4. Liu, T.X.; Wei, T.; Zhu, S. E.; Wang, G. W.; Jiao, M. Z.; Yang, S. F.; Bowles, F. L.;Olmstead, M. M.; Balch, A. L., Azide Addition to an EndohedralMetallofullerene: Formation of Azafulleroids of Sc3N@I-h-C-80. J Am Chem Soc2012, 134, (29), 11956-11959.

5. Li, F. B.;You, X.; Wang, G. W., Ferric Perchlorate-Mediated Synthesis of 1,2-FullerenolsC-60(OCOR) (OH). J Org Chem 2012, 77, (15), 6643-6647.

6. Li, F. B.;You, X.; Liu, T. X.; Wang, G. W., Fullerenyl Boronic Esters: FerricPerchlorate-Mediated Synthesis and Functionalization. Org Lett 2012, 14, (7),1800-1803.

7. Li, F.;Liu, T. X.; Wang, G. W., Synthesis of 60 Fullerene-Fused Sultones via SulfonicAcid Group-Directed C-H Bond Activation. Org Lett 2012, 14, (8), 2176-2179.

8. Li, D. D.;Yuan, T. T.; Wang, G. W., Palladium-Catalyzed Ortho-Arylation of Benzamides viaDirect sp(2) C-H Bond Activation. J Org Chem 2012, 77, (7), 3341-3347.

9. Wang, G.W.; Yuan, T. T.; Li, D. D., One-Pot Formation of C-C and C-N Bonds throughPalladium-Catalyzed Dual C-H Activation: Synthesis of Phenanthridinones. AngewChem Int Edit 2011, 50, (6), 1380-1383.

10. Wang, G. W.;Wang, C. Z.; Zou, J. P., Radical Reaction of 60 Fullerene with PhosphorusCompounds Mediated by Manganese(III) Acetate. J Org Chem 2011, 76, (15),6088-6094.

11. Wang, G. W.;Wang, C. Z.; Zhu, S. E.; Murata, Y., Manganese(III) acetate-mediated radicalreaction of 60 fullerene with phosphonate esters affording unprecedentedseparable singly-bonded 60 fullerene dimers. Chem Commun 2011, 47, (21),6111-6113.

12. Wang, G. W.;Miao, T., Palladium-Catalyzed Desulfitative Heck-Type Reaction of Aryl SulfinicAcids with Alkenes. Chem-Eur J 2011, 17, (21), 5787-5790.

13. Wang, G. W.;Liu, T. X.; Jiao, M. Z.; Wang, N.; Zhu, S. E.; Chen, C. B.; Yang, S. F.;Bowles, F. L.; Beavers, C. M.; Olmstead, M. M.; Mercado, B. Q.; Balch, A. L.,The Cycloaddition Reaction of I-h-Sc3N@C-80 with2-Amino-4,5-diisopropoxybenzoic Acid and Isoamyl Nitrite to Produce anOpen-Cage Metallofullerene. Angew Chem Int Edit 2011, 50, (20), 4658-4662.

14. Miao, T.;Wang, G. W., Synthesis of ketones by palladium-catalysed desulfitative reactionof arylsulfinic acids with nitriles. Chem Commun 2011, 47, (33), 9501-9503.

15. Liu, T. X.;Li, F. B.; Wang, G. W., Synthesis of 60 Fullerene-Fused Tetrahydronaphthaleneand Indane Derivatives via a Pathway Switched by Aluminum Chloride. Org Lett2011, 13, (22), 6130-6133.

16. Li, D. D.;Yuan, T. T.; Wang, G. W., Synthesis of isoindolinones via palladium-catalyzedC-H activation of N-methoxybenzamides. Chem Commun 2011, 47, (48), 12789-12791.

17. Wang, G. W.;Yuan, T. T., Palladium-Catalyzed Alkoxylation of N-Methoxybenzamides via Directsp(2) C-H Bond Activation. J Org Chem 2010, 75, (2), 476-479.

18. Li, F. B.;You, X.; Wang, G. W., Synthesis of Disubstituted 60 Fullerene-Fused Lactones:Ferric Perchlorate-Promoted Reaction of 60 Fullerene with Malonate Esters. OrgLett 2010, 12, (21), 4896-4899.

19. Li, F. B.;Liu, T. X.; You, X.; Wang, G. W., A Facile Access to 60 Fullerene-Fused1,3-Dioxolanes: Reaction of 60 Fullerene with Aldehydes/Ketones Promoted byFerric Perchlorate. Org Lett 2010, 12, (14), 3258-3261.

20. Zhu, B.;Wang, G. W., Palladium-Catalyzed Heteroannulation of 60 Fullerene with Anilidesvia C-H Bond Activation. Org Lett 2009, 11, (19), 4334-4337.

21. Wang, G. W.;Zhu, B., A facile access to 60 fullerene-fused delta-lactones: unexpectedreaction pathway of benzenediazonium-2-carboxylates controlled by organicbases. Chem Commun 2009, (13), 1769-1771.

22. Wang, G. W.;Lu, Y. M.; Chen, Z. X., 1,4-Fullerenols C60ArOH: Synthesis andFunctionalization. Org Lett 2009, 11, (7), 1507-1510.

23. Wang, G. W.;Gao, J., Selective Formation of Spiro Dihydrofurans and Cyclopropanes ThroughUnexpected Reaction of Aldehydes with 1,3-Dicarbonyl Compounds. Org Lett 2009,11, (11), 2385-2388.

24. Li, F. B.;Liu, T. X.; Huang, Y. S.; Wang, G. W., Synthesis of Fullerene-Fused Lactonesand Fullerenyl Esters: Radical Reaction of 60 Fullerene with Carboxylic AcidsPromoted by Manganese(III) Acetate and Lead(IV) Acetate. J Org Chem 2009, 74,(20), 7743-7749.

25. Wang, G. W.;Dong, Y. W.; Wu, P.; Yuan, T. T.; Shen, Y. B., Unexpected solvent-freecycloadditions of 1,3-cyclohexanediones to 1-(pyridin-2-yl)-enones mediated bymanganese(III) acetate in a ball mill. J Org Chem 2008, 73, (18), 7088-7095.

26. Li, F. B.;Liu, T. X.; Wang, G. W., Synthesis of fullerooxazoles: Novel reactions of 60fullerene with nitriles promoted by ferric perchlorate. J Org Chem 2008, 73,(16), 6417-6420.

27. Gao, J.;Wang, G. W., Direct oxidative amidation of aldehydes with anilines undermechanical milling conditions. J Org Chem 2008, 73, (7), 2955-2958.

28. Wu, X. L.;Wang, G. W., Aminochlorination in water: First Bronsted acid-promoted synthesisof vicinal chloramines. J Org Chem 2007, 72, (24), 9398-9401.

29. Wang, G. W.;Li, F. B.; Xu, Y., Novel functionalizations of 60 fullerene-fused lactones. JOrg Chem 2007, 72, (13), 4774-4778.

30. Wang, G. W.;Li, F. B.; Chen, Z. X.; Wu, P.; Cheng, B.; Xu, Y., Synthesis of 60 fullereneacetals and ketals: Reaction of 60 fullerene with aldehydes/ketones andalkoxides. J Org Chem 2007, 72, (13), 4779-4783.

1997-2006

1. Guan-Wu Wang, Koichi Komatsu,* Yasujiro Murata, and Motoo Shiro, "Synthesis and X-Ray Structure of Dumb-Bell-Shaped C120", Nature 1997, 387, 583-586. (cover title, news reported by C & EN, news reported by Kyoto Newspaper)

2. Mark S. Meier,* Guan-Wu Wang, Robert C. Haddon, Carolyn Pratt. Brock, Michael A. Lloyd, and John P. Selegue, "Benzyne Adds Across a Closed 5-6 Ring Fusion in C70: Evidence for Bond Delocalization in Fullerenes", J. Am. Chem. Soc. 1998, 120, 2337-2342.

3. Guan-Wu Wang,* Xin-Hao Zhang, Huan Zhan, Qing-Xiang Guo, and Yun-Dong Wu, “Accurate Calculation, Prediction, and Assignment of 3He NMR Chemical Shifts of Helium-3-Encapsulated Fullerenes and Fullerene Derivatives”, J. Org. Chem. 2003, 68, 6732-6738.

4. Guan-Wu Wang, “Fullerene Mechanochemistry”, in Encyclopedia of Nanoscience and Nanotechnology, H. S. Nalwa, Ed., American Scientific Publishers: Stevenson Ranch, Vol. 3, p. 557-565, 2004. (invited book chapter).

5. Ze Zhang, Guan-Wu Wang,* Chun-Bao Miao, Ya-Wei Dong, and Ye-Bing Shen, “Solid-state Radical Reactions of 1,3-Cyclohexanediones with in situ Generated Imines Mediated by Manganese(III) Acetate under Mechanical Milling Conditions”, Chem. Commun. 2004, 1832-1833.

6. Zhong-Xiu Chen, and Guan-Wu Wang,* “One-Pot Sequential Synthesis of Acetoxylated [60]Fullerene Derivatives”, J. Org. Chem. 2005, 70, 2380-2383.

7. Guan-Wu Wang,* Jia-Xing, Li, Yu-Jin Li, and You-Cheng Liu, “Novel Reactions of [60]Fullerene with Amino Acid Esters and Carbon Disulfide”, J. Org. Chem. 2006, 71, 680-684.

8. Guan-Wu Wang,* Fa-Bao Li, Ting-Hu Zhang, “[60]Fullerene-Fused Lactones: Manganese(III) Acetate-Mediated Synthesis and Novel Reductive Ring Opening”, Org. Lett. 2006, 8, 1355-1358.

9. Guan-Wu Wang,* Hai-Tao Yang, Ping Wu, Chun-Bao Miao, and Yu Xu, “Novel Cycloaddition Reaction of [60]Fullerene with Carbonyl Ylides Generated from Epoxides”, J. Org. Chem. 2006, 71, 4346-4348.


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